Data underlying the publication: Metastable Oxygen-Induced Light-Enhanced Doping in Mixed Sn-Pb Halide Perovskites
DOI: 10.4121/5ae647ce-65a3-46a7-828c-207e85b86962
Datacite citation style
Dataset
Data for SSMC and TRMC results, XRD, UV-Vis-NIR spectroscopy and XPS results in the main manuscript and Supporting Information published with DOI: 10.1021/jacs.4c08924.
The raw data were collected in the years 2023-2024, using various structural, compositional, and opto-electronic characterization methods on solution-based spin-coated mixed tin-lead (Sn-Pb) perovskite thin films. All measurements were conducted at room temperature, after varying exposure to oxygen and/or light, or after rest in nitrogen, to study the metastable oxygen-induced light-enhanced doping in the layers. More specifically, all SSMC and TRMC measurements were conducted under nitrogen. The xy data obtained from X-ray diffraction (XRD), UV-Vis-NIR spectroscopy, and X-ray photoelectron spectroscopy (XPS) were imported into Igor Pro (Wavemetrics). In Igor Pro, these xy data are stored as "waves," corresponding to the values on the x and y axes in the plots. Data for Steady State Microwave Conductance (SSMC) and Time-Resolved Microwave Conductivity (TRMC) were collected directly as waves in Igor Pro on the computers connected to the respective microwave-based setups. Igor Pro was used to generate all data plots.
For further information on file formats and naming, the units and abbreviations used for all measured values and labels, and instructions for opening or modifying Igor Pro files, please refer to the README.pdf included in the dataset. It is strongly recommended to consult the corresponding publication for guidance on the files in these datasets, as each file name includes a reference to its associated figure. The main manuscript and Supporting Information of the publication contains details about the characterization instruments and additional data processing specifics.
History
- 2025-11-07 first online, published, posted
Publisher
4TU.ResearchDataFormat
Igorfile/pxpAssociated peer-reviewed publication
Metastable Oxygen-Induced Light-Enhanced Doping in Mixed Sn-Pb Halide PerovskitesFunding
- Where do we lose potential in perovskite solar cells? (grant code OCENW.KLEIN.076) [more info...] Dutch Research Council (NWO)
Organizations
TU Delft, Faculty of Applied Sciences, Department of Chemical Engineering, Opto-electronic Materials GroupDATA
Files (34)
- 68,144 bytesMD5:
4734012351c7d72af648165f579f0b95README.pdf - 1,869,410 bytesMD5:
6ed9d9653e8ac9c441dc492056c71226Changeindarkconductivity_Sn05_oxy-light-oxylight-restN2_Fig1+FigS13.pxp - 1,852,487 bytesMD5:
676ef83b9b0f8503e342af670d5eb70aChangeindarkconductivity_Sn05_oxy-light-oxylight_Fig2.pxp - 774,531 bytesMD5:
4fe51735341454c5068c75e6118468e4KfactorvsDarkconductivity_FigS4.pxp - 280,473 bytesMD5:
aaadac9da7303257cd37d5be2d1d65adLEDTRMC_FigS7.pxp - 851,570 bytesMD5:
fdc29f800b69cc83e283ddf6c9b4e3e3SSMC+TRMC_Sn05_effectlongrestN2_FigS9.pxp - 534,757 bytesMD5:
962dcd524b80cd79bca917f88c509a64SSMC_ALDSn05_oxy_Fig1.pxp - 1,200,357 bytesMD5:
e90c19cebf376d2b85983a2a97a09969SSMC_MASn05_oxy-restN2_FigS12.pxp - 862,868 bytesMD5:
687e60141a87e2097b7224a435f5747eSSMC_MASn05_oxylight-restN2_FigS12.pxp - 200,681 bytesMD5:
f61536e5777185a9ff0d9c1694d08deaSSMC_QuartzPerovskite_FigS1.pxp - 1,435,907 bytesMD5:
1c1910a4fbbc7f64342ace430c20a33eSSMC_Sn02_oxy-restN2_FigS10.pxp - 1,006,705 bytesMD5:
f36c839ac4480fdd67dc6b778f76c8a6SSMC_Sn05_effectlaserN2orOxy_FigS6.pxp - 611,108 bytesMD5:
10e55a0840d1dea33f2c9e2fbdc68fc5SSMC_Sn05_light-restN2_FigS11.pxp - 1,825,721 bytesMD5:
1bdb1281bde9b66110900a95958b4c93SSMC_Sn05_oxy-restN2_Fig1+FigS10+FigS11.pxp - 1,531,240 bytesMD5:
57d6ec2abcf63da4980032a20f4a37ecSSMC_Sn05_oxylight-restN2_FigS11.pxp - 507,319 bytesMD5:
6e206126ecd69eed0e879d79e8ae2e5aSSMC_Sn0_oxy_FigS10.pxp - 229,024 bytesMD5:
40367848fd4cba6baf63caa5a6510957SSMC_Sn1_oxy_FigS10.pxp - 1,859,491 bytesMD5:
beb26da70cb639bc34e50e601e3a8ce9TOC.pxp - 613,849 bytesMD5:
5a709930a3f652b32186adb60d28d51cTRMC_Sn05_light-restN2_Fig3+FigS13.pxp - 1,823,889 bytesMD5:
63daf3946125fcfe3a48334f0d46a741TRMC_Sn05_oxy-restN2_Fig3+FigS13.pxp - 563,526 bytesMD5:
c6a8a1ec0785fb14bb417f4c7bbfd7d8TRMC_Sn05_oxy_Fig3+FigS14+FigS15.pxp - 1,536,243 bytesMD5:
4152aa103b582ca7655d8af6b445d5c0TRMC_Sn05_oxylight-restN2_Fig3+FigS3+FigS13.pxp - 119,495 bytesMD5:
a9a4fcfa350af690ccc8a732101c61b7UV-Vis_Sn05_longoxy-restN2_FigS22.pxp - 84,012 bytesMD5:
23206d9774a208ad48a539e7fb722c39UV-Vis_Sn05_longoxylight-restN2_Fig4.pxp - 50,652 bytesMD5:
34bc04eb640f66368cbbc56df397b229UV-Vis_Sn05_oxy-light-oxylight-restN2_FigS21.pxp - 102,480 bytesMD5:
f40395dcd494c3b4d025ea12abb3a00eUV-Vis_Sn0Sn02Sn05Sn1_FigS20.pxp - 415,020 bytesMD5:
303bfc4b0a73f731a5b4be534ccb414dXPS_Cs3dSn3dPb4fI3dO1s_depthprofiling_Sn05_longoxylight-restN2_Fig4+FigS23.pxp - 420,514 bytesMD5:
1153829f5a49968537bfcbf6616fc025XPS_Cs3dSn3dPb4fI3dO1s_Sn05_longoxy-restN2_FigS24.pxp - 390,964 bytesMD5:
cff4a9e5c9f103a35df9c8b1175fd7a4XPS_Cs3dSn3dPb4fI3dO1s_Sn05_longoxylight-restN2_FigS23.pxp - 72,842 bytesMD5:
7a743eca979c6d8d602c987b25c9d209XPS_Sn3dO1s_peakfitting_Sn05_longoxylight-restN2_Fig4.pxp - 482,802 bytesMD5:
f79e0c85192c2318ca605f84a61bcfe0XRD+GIXRD_Sn05_longoxylight-restN2_Fig4+FigS19.pxp - 521,802 bytesMD5:
7261e7143cd8d652f13cc8f0def79d99XRD_Sn05_longoxy-restN2_FigS18.pxp - 654,324 bytesMD5:
190a444538b591449cbcb3d5d2461be7XRD_Sn05_oxy-light-oxylight-restN2_FigS17.pxp - 1,460,960 bytesMD5:
de1d121ef42a24442ea1c9340628c60dXRD_Sn0Sn02Sn05Sn1_FigS16.pxp -
download all files (zip)
26,815,167 bytes unzipped





