Data underlying thesis chapter and paper: Fluorine-free Lithium Ion Batteries: A Working Alternative
DOI: 10.4121/4b3fd60f-242f-47f3-b5d8-cf8816759ea2
Datacite citation style
Dataset
Repository for paper Fluorine-free Lithium Ion Batteries: A Working Alternative. Abstract of paper:
Current commercial battery designs contain fluorinated materials as binders and electrolyte salts to ensure high electrochemical and thermal stability. Upcoming regulations in Europe and the US restrict the manufacturing of such materials, as their persistence in drinking water and soil can cause long term ecological harm. In this perspective, we showcase a completely fluorine-free battery design which has similar performance compared to commercial standards, while using aqueous processed LiNi0.8Mn0.1Co0.1O2 (NMC811) and graphite as cathode and anode active materials respectively. The cell shows 98% retained capacity after 600 cycles at room temperature, indicating good stability of active material with non-fluorinated binders. The charge rate performance (69% retained capacity at 1C, 1.5 mAh/cm2) could be improved by combining two fluorine-free salts (67% retained capacity at 1C with 2.5 times the loading, 3.3 mAh/cm2). This work illustrates that fluorine-free cell designs show good battery performance over awide potential window.
History
- 2025-05-15 first online, published, posted
Publisher
4TU.ResearchDataFormat
ASCII .txt, Origin .opju, MACCOR battery cycling .three digit number, ZView .z, Excel .xlsxFunding
- SOLiDIFY (grant code 875557) [more info...] Horizon 2020
Organizations
TU Delft, Faculty of Applied Sciences, Department of Chemical EngineeringDATA
Files (11)
- 824,175 bytesMD5:
840c23cc10f459626df7b966556faa9eCV stepAmp and EIS origin.opju - 481,600 bytesMD5:
707eae64b59fdea2a3f3f455620c921eLiBOBcell.opju - 416,152 bytesMD5:
eeeecdc304062b94e6c24cf49c6822a0LiBOBLiClO4cell.opju - 900 bytesMD5:
32f098dd8292b6f57e749c01b838b6a9META Battery Cycling.txt - 803 bytesMD5:
026abfdca7a91aa3533db31885262976META main.txt - 1,575 bytesMD5:
29dcb3680e453bb56b196a3e8d4e02a9META XPS.txt - 1,139 bytesMD5:
d060e0059068baa1ed5a38cb3e846676META Zview.txt - 88,034 bytesMD5:
931ae65a3f4fa250e289721b8f2f80baRateComparison.opju - 89,354 bytesMD5:
0821d4d11097b96b4b3d6a9a8e267db5RateComparison.opju - 90,847,988 bytesMD5:
08da65dd9af7bbc36733c458907a6dcfRepository FFree.zip - 375,398 bytesMD5:
cca488eadfeed84fa51f01afbeb7d6bfXPS LiBOB and LiClO4 cells.opju -
download all files (zip)
93,127,118 bytes unzipped





