TY - DATA
T1 - Data underlying the publication: "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle"
PY - 2023/10/31
AU - Benjamin Spitzbarth
AU - Anastasiia Sharko
AU - Thomas Hermans
AU - Rienk Eelkema
UR - 
DO - 10.4121/d65cfd80-74a5-4018-974c-8d82c1f51ab0.v1
KW - Organic Chemistry
KW - Reaction Cycle
KW - Chemical Reaction Network
KW - Michael acceptor
KW - Oxidation chemistry
KW - Shunt
N2 - <p><span style="background-color: rgb(255, 250, 234);">Complete set of data underlying the experiments conducted in "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle". The aim of this publication is to demonstrate a new use of beta'-substituted Michael acceptors (MAs). A new Chemical Reaction Network (CRN) is based based on addition-elimination- as well as oxidation-chemistry. An amine-functionalised MA can be turned into a thiol-functionalised MA with a thiol. This deactivated MA can be reactivated with different oxidants, making it prone to amine-readdition, recovering the starting material. We show that different oxidants lead to different pathways of this CRN with different side products and kinetics. Further, we show a flow-controlled switching between different species of this CRN, offering the ability to recover the starting material and recycle the waste species (disulfide).</span></p><p><span style="background-color: rgb(255, 250, 234);">Please refer to the readme file, explaining the experiment identifiers and conditions of each experiment.</span></p>
ER -