TY - DATA
T1 - Data underlying the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network
PY - 2022/09/26
AU - Benjamin Klemm
AU - Irene Piergentili
AU - Reece Lewis
AU - Rienk Eelkema
UR - https://data.4tu.nl/articles/dataset/Data_underlying_the_paper_Temporally_programmed_polymer-solvent_interactions_using_a_chemical_reaction_network/21197290/1
DO - 10.4121/21197290.v1
KW - Chemical reaction networks (CRNs)
KW - polymer-solvent interactions
KW - stimuli-responsive materials
KW - autonomously responding materials
N2 - <p>The data underlines the paper: <strong>Temporally programmed polymer-solvent interactions using a chemical reaction network</strong>. In this work a new modular chemical reaction network (CRN) was developed, which enables reversible formation of positive charges on a tertiary amine substrate, which are removed using nucleophilic signals that control the deactivation kinetics. The modular nature of the CRN enables incorporation in diverse polymer materials, leading to a temporally programmed transition from collapsed and hydrophobic to solvated, hydrophilic polymer chains by controlling polymer-solvent interactions. Depending on the layout of the CRN, we can create stimuli-responsive or autonomously responding materials.</p>
ER -