%0 Generic
%A Klemm, Benjamin
%A Piergentili, Irene
%A Lewis, Reece
%A Eelkema, Rienk
%D 2022
%T Data underlying the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network
%U https://data.4tu.nl/articles/dataset/Data_underlying_the_paper_Temporally_programmed_polymer-solvent_interactions_using_a_chemical_reaction_network/21197290/1
%R 10.4121/21197290.v1
%K Chemical reaction networks (CRNs)
%K polymer-solvent interactions
%K stimuli-responsive materials
%K autonomously responding materials
%X <p>The data underlines the paper: <strong>Temporally programmed polymer-solvent interactions using a chemical reaction network</strong>. In this work a new modular chemical reaction network (CRN) was developed, which enables reversible formation of positive charges on a tertiary amine substrate, which are removed using nucleophilic signals that control the deactivation kinetics. The modular nature of the CRN enables incorporation in diverse polymer materials, leading to a temporally programmed transition from collapsed and hydrophobic to solvated, hydrophilic polymer chains by controlling polymer-solvent interactions. Depending on the layout of the CRN, we can create stimuli-responsive or autonomously responding materials.</p>
%I 4TU.ResearchData