%0 Generic
%A Spitzbarth, Benjamin
%A Sharko, Anastasiia
%A Hermans, Thomas
%A Eelkema, Rienk
%D 2023
%T Data underlying the publication: "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle"
%U 
%R 10.4121/d65cfd80-74a5-4018-974c-8d82c1f51ab0.v1
%K Organic Chemistry
%K Reaction Cycle
%K Chemical Reaction Network
%K Michael acceptor
%K Oxidation chemistry
%K Shunt
%X <p>Complete set of data underlying the experiments conducted in "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle". The aim of this publication is to demonstrate a new use of beta'-substituted Michael acceptors (MAs). A new Chemical Reaction Network (CRN) is based based on addition-elimination- as well as oxidation-chemistry. An amine-functionalised MA can be turned into a thiol-functionalised MA with a thiol. This deactivated MA can be reactivated with different oxidants, making it prone to amine-readdition, recovering the starting material. We show that different oxidants lead to different pathways of this CRN with different side products and kinetics. Further, we show a flow-controlled switching between different species of this CRN, offering the ability to recover the starting material and recycle the waste species (disulfide).</p><p>Please refer to the readme file, explaining the experiment identifiers and conditions of each experiment.</p>
%I 4TU.ResearchData