Complete set of data underlying the experiments conducted in "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle". The aim of this publication is to demonstrate a new use of beta'-substituted Michael acceptors (MAs). A new Chemical Reaction Network (CRN) is based based on addition-elimination- as well as oxidation-chemistry. An amine-functionalised MA can be turned into a thiol-functionalised MA with a thiol. This deactivated MA can be reactivated with different oxidants, making it prone to amine-readdition, recovering the starting material. We show that different oxidants lead to different pathways of this CRN with different side products and kinetics. Further, we show a flow-controlled switching between different species of this CRN, offering the ability to recover the starting material and recycle the waste species (disulfide).
Please refer to the readme file, explaining the experiment identifiers and conditions of each experiment.
" authors: - family-names: Spitzbarth given-names: Benjamin - family-names: Sharko given-names: Anastasiia - family-names: Hermans given-names: Thomas - family-names: Eelkema given-names: Rienk title: "Data underlying the publication: "Redox-Controlled Shunts in a Synthetic Chemical Reaction Cycle"" keywords: version: 1 identifiers: - type: doi value: 10.4121/d65cfd80-74a5-4018-974c-8d82c1f51ab0.v1 license: CC BY 4.0 date-released: 2023-10-31