cff-version: 1.2.0 abstract: "

The data underlines the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network. In this work a new modular chemical reaction network (CRN) was developed, which enables reversible formation of positive charges on a tertiary amine substrate, which are removed using nucleophilic signals that control the deactivation kinetics. The modular nature of the CRN enables incorporation in diverse polymer materials, leading to a temporally programmed transition from collapsed and hydrophobic to solvated, hydrophilic polymer chains by controlling polymer-solvent interactions. Depending on the layout of the CRN, we can create stimuli-responsive or autonomously responding materials.

" authors: - family-names: Klemm given-names: Benjamin orcid: "https://orcid.org/0000-0002-8758-5771" - family-names: Piergentili given-names: Irene orcid: "https://orcid.org/0000-0002-2220-4157" - family-names: Lewis given-names: Reece orcid: "https://orcid.org/0000-0001-5848-5248" - family-names: Eelkema given-names: Rienk orcid: "https://orcid.org/0000-0002-2626-6371" title: "Data underlying the paper: Temporally programmed polymer-solvent interactions using a chemical reaction network" keywords: version: 1 identifiers: - type: doi value: 10.4121/21197290.v1 license: CC BY-NC 4.0 date-released: 2022-09-26